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Synthesis of a chiral artificial receptor with catalytic activity in Michael additions and its chiral resolution by a new methodology. The corrections, fitted to a set of 28 reactions, are temperature-independent and reduce the mean absolute deviation on E(a) to 0.7 kJ mol(-1) and to 0.05 for log A. Patients with a diagnosis of IBD during 1999-2009 were identified by at least one ICD-9 code for CD (555.x) or UC (556.x) at the Houston and Ann Arbor VA Medical Centers and confirmed by generic viagra 25mg chart review. There is a steep temperature rise to normal chromospheric temperatures at a height of 900 to 1100 kilometers.

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